Synthesis and characterization of porous platelet-shaped α-Bi<Subscript>2</Subscript>O<Subscript>3</Subscript> with enhanced photocatalytic activity for 17α-ethynylestradiol

The porous platelet-shaped α-Bi₂O₃ photocatalyst was successfully synthesized by a novel hydrothermal–calcination method assisted with ethylenediamine and polyvinylpyrrolidone. The physical and chemical properties of α-Bi₂O₃ photocatalyst were characterized based on XRD, XPS, SEM, TEM, EDS, UV–Vis DRS, and PL techniques. The influence of preparation conditions on the formation of α-Bi₂O₃ photocatalyst was investigated, and the effect of catalyst dosage and pH value on the EE2 removal rate was also investigated. The synthesized porous platelet-shaped α-Bi₂O₃ photocatalyst exhibited excellent photocatalytic activity for 17α-ethynylestradiol (EE2), and 97.8% of EE2 was removed after 75 min of visible light irradiation using α-Bi₂O₃ as photocatalyst. The reaction rate constant over the porous platelet-shaped α-Bi₂O₃ photocatalyst was 11.6 and 11.4 times of that of traditional α-Bi₂O₃ and N-TiO₂, respectively. The possible photocatalytic mechanism has been discussed on the basis of the theoretical calculation and the experimental results. The porous platelet-shaped α-Bi₂O₃ was a stable and efficient photocatalyst, proving that it is a promising photocatalyst.     

An analysis of discontinued journals by Scopus

Researchers continually strive to communicate their findings to peers, hoping to receive recognition for their contribution in a not-so-distant future. The prevailing idea of “publish or perish” becomes imperative when researchers are applying for competitive grants or academic promotions. Choosing a suitable journal has become an important issue as thousands of journals are available. One of the aspects considered by researchers is the journal’s indexation status. Scopus continuously evaluates journals submitted by publishers for indexation, and later, to verify if quality is maintained. During this re-evaluation process, some publication concerns may be raised at journal or publisher level. Consequently, Scopus periodically issues a list of discontinued journals. However, not all journals update their websites in order to inform readers that they have been discontinued. This study shows that 56 journals that were discontinued in 2016 currently affirm on their websites that they are indexed by Scopus. In addition, another 20 journals discontinued in 2016, which do not specifically state that they are indexed by Scopus, include a widget from SCImago that may generate confusion about their current indexing situation. For some journals it seems that the emphasis is placed more on the publishing end of the business than the dissemination of research findings. This study shows that regular updates are among the responsibilities that editorial teams must maintain to ensure the quality and accuracy of the information posted on journal websites.     

Exploring the recovery of fatigue damage in bituminous mixtures: the role of rest periods

Recovery capability of bituminous materials plays a significant role in the development of new technologies for extending the service life of asphalt pavements. This capability originates from various phenomena such as thixotropy, cooling, relaxation of hardening, or healing. However, their real effect on mechanical response is not clear. This article aims to investigate how rest periods (RPs) available between traffic loads can contribute to the damage recovery of bituminous materials. For this purpose, different types and durations of RPs were applied during the laboratory evaluation of fatigue resistance of these materials using the University of Granada Fatigue Asphalt Cracking Test method. The results indicate that the addition of RPs to the loading regime could lead to an extension in the fatigue life of bituminous materials. Additionally, an increase in the RP duration showed a positive impact on the resistance of the materials against cyclic loading. Nonetheless, these benefits are not only related to the recovery of lost properties during RPs, but also a growth in the amount of plastic deformations as a result of the applying RPs could delay the appearance of damages (i.e. cracking). Consequently, the bituminous material can tolerate a higher number of load cycles during fatigue test.     

A 2D topology optimisation algorithm in NURBS framework with geometric constraints

In this paper, the solid isotropic material with penalisation (SIMP) method for topology optimisation of 2D problems is reformulated in the non-uniform rational BSpline (NURBS) framework. This choice implies several advantages, such as the definition of an implicit filter zone and the possibility for the designer to get a geometric entity at the end of the optimisation process. Therefore, important facilities are provided in CAD postprocessing phases in order to retrieve a consistent and well connected final topology. The effect of the main NURBS parameters (degrees, control points, weights and knot-vector components) on the final optimum topology is investigated. Classic geometric constraints, as the minimum and maximum member size, have been integrated and reformulated according to the NURBS formalism. Furthermore, a new constraint on the local curvature radius has been developed thanks to the NURBS formalism and properties. The effectiveness and the robustness of the proposed method are tested and proven through some benchmarks taken from literature and the results are compared with those provided by the classical SIMP approach.     

Design of biorefinery systems for conversion of corn stover into biofuels using a biorefinery engineering framework

Unlocking the potential and value of lignocellulosic residues is an important step in making biorefineries economically and environmentally promising. This calls for a holistic and systematic approach in designing sustainable industrial systems. In this work, biorefinery systems via biochemical route (acetone–butanol–ethanol or ABE system) and thermochemical route (gasification and mixed alcohols or GMA system) for converting corn stover into biofuels have been designed using a Sustainable Engineering Framework. The framework involves eight main steps: (1) design problem definition, (2) data collection, (3) process synthesis and simulation, (4) process integration, (5) resource recovery from residues, (6) utility system design, (7) economic and environmental modelling and (8) economic value and environmental impact margin analysis for decision making. Consideration of resource recovery from biorefinery waste streams has proven to be the key in making biorefineries self-sustaining and with low environmental impacts. Simultaneous economic and environmental feasibility assessment at the early stage of process design is highly envisaged. The cost of biofuel production in the ABE system has been found to be 49.2 US$/GJ and 69.9 US$/GJ in the GMA system. The greenhouse gas emissions are 46.2 g CO₂-eq/GJ for ABE and 19.0 g CO₂-eq/GJ for GMA, lower than gasoline (85 g CO₂-eq/GJ). The GMA system is not economically compelling though with high environmental benefit, while the ABE system has shown to be both economically and environmentally feasible.     

A New Method for Siting Hazardous Units in Chemical Process Facilities Which Minimizes Risk at Least Cost: RIDIMPUS

A new method, RIsk and DIstance Minimization in Process Units Siting (RIDIMPUS), is presented with which hazardous units can be sited in a chemical process facility in a manner that the risk of accidents involving the hazardous units as also the cost of spacing the units is minimized. To achieve this, safety and cost factors were modeled using various governing parameters and then expressions were designed to integrate the safety and the economic concerns to form model equations, inequalities and disjunctions. The resulting nonlinear programming model is solvable by using algorithms and solvers on any common desktop computer, thereby providing an optimal and prompt solution.     

Failure Analysis of Fan Motor Shafts of a Tunnel Dryer

This article details the analysis of two conducting shafts operating on blowers of a tunnel dryer. A deductive analysis was applied looking toward a successful recognition of root cause(s), where based on knowledge of background, and failure characteristics, multiple hypothesis are exposed that are further confirmed or rejected according to different tests, material analysis or maintenance history. In both shafts, failure arises from inadequate repairing. In order to confirm this, the failure analysis methodology included the following steps: technical review, visual inspection, fractography, penetrating inks, metallography, optic microscopy and stress analysis. Evidence obtained through these techniques indicates a fatigue failure induced by inadequate repairing procedures; therefore, main recommendation is to take the necessary precautions in order to guarantee minimal alterations on shaft geometry or material microstructure.     

Screen printing for support-pillar placement for vacuum glazing and the effects of pillar spacing on strength properties

Maintaining a vacuum between the two glasses to maximize the heat insulating performance, it is indispensable to array the pillar for the vacuum glazing to maintain the vacuum gap. In this paper, to investigate the effect of the spacing of the pillars arranged using the screen printing method on the strength of the glass, a bending strength test was carried out by design and fabricating a ROR bending strength test jig based on the Euro standard. In the strength test results, the experimental results were analyzed using the Weibull distribution, which is a statistical analysis method mainly used for evaluating the breaking strength of brittle material. Based on the analysis results, the placement spacing of the pillars proved validity for maintaining the vacuum glass gaps.     

Designing a secure designated server identity-based encryption with keyword search scheme: still unsolved

There exist only a few papers in the literature which target the problem of “proposing a secure designated server identity-based encryption with keyword search scheme.” In this paper, we prove that they all suffer from security issues, and therefore, this challenging problem still remains open.     

Price competition between a macrocell and a small-cell service provider with limited resources and optimal bandwidth user subscription: a game-theoretical model

The ever-increasing demand for higher data rates in wireless commutations provides a rationale for small cells deployment. While the physical and technological aspects of small-cell networks have been extensively studied in recent years, the economic analysis has received much less attention. We focus on the economic rationale for a small-cell service provider (SSP) operating a market where an incumbent macrocell service provider (MSP) exists, and competition develops. We analyze such scenario for the case of fixed users by means of Game Theory, specifically through a two-stage game: in the first stage each service provider posts its price according to a Stackelberg game where the MSP is the leader and the SSP is the follower; and, in the second stage, each user chooses both which provider to subscribe to and the optimal amount of bandwidth. A subgame perfect Nash equilibrium is used as a solution concept, and it is derived analytically. We show that the SSP has an incentive to operate in the market and its profit gets higher as SSP’s resources increase. Furthermore, users benefit from SSP’s operation, which may provide a rationale for a regulatory authority to grant the SSP access to the market, despite the fact that MSP’s profit is harmed. Finally, we identify two modes of operation of the system, which depend on the SSP coverage: one where SSP’s deployment is limited and the MSP strategy is not affected by SSP competition and takes only the users outside the SSP coverage; and another, where the SSP covers a large area and the MSP competes against the SSP taking a fraction of the users inside the small cells.